How do I choose between my boyfriend and my best friend? Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors. ), *Thermodynamics and Kinetics of Organic Reactions, *Free Energy of Activation vs Activation Energy, *Names and Structures of Organic Molecules, *Constitutional and Geometric Isomers (cis, Z and trans, E), *Identifying Primary, Secondary, Tertiary, Quaternary Carbons, Hydrogens, Nitrogens, *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections), *Cyclohexanes (Chair, Boat, Geometric Isomers), Stereochemistry in Organic Compounds (Chirality, Stereoisomers, R/S, d/l, Fischer Projections). These cookies will be stored in your browser only with your consent. In India on the occasion of marriages the fireworks class 12 chemistry JEE_Main, The alkaline earth metals Ba Sr Ca and Mg may be arranged class 12 chemistry JEE_Main, Which of the following has the highest electrode potential class 12 chemistry JEE_Main, Which of the following is a true peroxide A rmSrmOrm2 class 12 chemistry JEE_Main, Which element possesses the biggest atomic radii A class 11 chemistry JEE_Main, Phosphine is obtained from the following ore A Calcium class 12 chemistry JEE_Main, Differentiate between the Western and the Eastern class 9 social science CBSE, NEET Repeater 2023 - Aakrosh 1 Year Course, CBSE Previous Year Question Paper for Class 10, CBSE Previous Year Question Paper for Class 12. If true enter 1 else 0. Sonoda, N.; Kondo K.; Nagano, K.; Kambe, N.; Morimoto, F. Angewandte Chemie International Edition English 1980, vol. 9 Which has a higher boiling point H2O or H2S? Q. Amongst H2O,H2S,H2Se and H2Te, the 1one with the highest boiling point is. Study with Quizlet and memorize flashcards containing terms like Arrange these compounds in order of increasing boiling point H2S, H2Se, H2O (a) H2O < H2Se < H2S (b) H2Se < H2S < H2O (c) H2Se < H2O < H2S (d) H2S < H2Se < H2O (e) H2O < H2S < H2Se, Which of the following would be expected to form a homogenous solution? Which of the following has highest boiling point H2O H2S H2Se? Why does H2S have a lower boiling point than H2O and H2Se? 6 Which water has the highest boiling point? These cookies ensure basic functionalities and security features of the website, anonymously. -42.25F (-41.25C) High boiling point and low melting point. Why H2S has lower boiling point than H2O? This cookie is set by GDPR Cookie Consent plugin. Water has strong hydrogen bonds between molecules. 5 Why does H2Se have a higher boiling point than H2S? Answer (1 of 14): Summary; Oxygen is more electronegative than sulphur Thus, the dipoles (which have a lot to do with bonding) are more strongly charged in H2O Thus the intermolecular bonds formed in H2O are stronger Thus it takes more energy to break those bonds in H2O Thus, to break those . H2Se has the higher boiling point because it has a larger mass and more electrons. asked Apr 21, 2019 in Chemistry by Simrank (72.5k points) p - block element . Which has the highest boiling point H2O H2S or H2Se? > H2S < H2Se < H2Te < H2O Thi O This is the correct boiling point order. -42.25F (-41.25C) We don't save this data. Advertisement cookies are used to provide visitors with relevant ads and marketing campaigns. At 1atm, the melting point of H2O(water) is 0 degrees celcius and the boiling point is 100 degrees celcius. We also use third-party cookies that help us analyze and understand how you use this website. what is the. Boiling points of the lower hydrides follow the order we would expect for dispersion forces. 1. It adds across alkenes. 3 Does H2S have the highest boiling point? Hydrogen sulfide - Thermophysical Properties, STP - Standard Temperature and Pressure & NTP - Normal Temperature and Pressure, Heat (enthalpy) of sublimation,at -145F/-98C, Specific heat capacity, Cp (liquid) at 20 bara, Specific heat capacity, Cv (liquid) at 20 bara, Specific Gravity (liquid) (relativ to water), Specific Heat Ratio (liquid) - CP/CV at 20 bara, Specific Volume (liquid) at -121.9 F/-85.5C. What is the formula for calculating solute potential? The boiling point of hydrogen compounds of group 16 is into the order of H2O > H2S . [4][5] Even at extremely low concentrations, this compound has a very irritating smell resembling that of decayed horseradish or 'leaking gas', but smells of rotten eggs at higher concentrations. I'm taking A level economics and business studies. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Please read AddThis Privacy for more information. Elemental selenium can be recovered from H2Se through a reaction with aqueous sulfur dioxide (SO2). Postby Madison Gil 3D Sat Dec 08, 2018 5:09 pm, Postby Austin Clack Sat Dec 08, 2018 6:28 pm, Postby Rami_Z_AbuQubo_2K Sun Dec 09, 2018 5:13 pm, Postby Anjali_Kumar1F Sun Dec 09, 2018 5:41 pm, Postby 604656370 Mon Dec 10, 2018 12:35 am, Return to Properties & Structures of Inorganic & Organic Acids, Users browsing this forum: No registered users and 0 guests. H2Te because of higher molecular weight. Hydrogen selenide is an inorganic compound with the formula H2Se. Press ESC to cancel. Discuss the forces present in H2S and H2Se. molecular weight in essentially that of a single molecule. Which of the following has lowest boiling point H2O H2S H2Se? The cookies is used to store the user consent for the cookies in the category "Necessary". Why does H2S have a lower boiling point than water? In water, the hydrogens are bound to oxygen, a strongly electronegative element. Since electrons are constantly moving, at any given time, one atom will be more electronegative than the other atom. Can someone explain to me why H2Se would have the higher boiling point? Hydrogen sulfide is a colorless gas with an offensive stench and is said to smell like rotten eggs. The Cambridge College Hurt/Heal Game [part 2], Concept of research within humanities is baffling, Official UCL 2023 Undergraduate Applicants Thread. Advertisement cookies are used to provide visitors with relevant ads and marketing campaigns. Among H2O, H2, H2Se and H2 Te, the one with highest boiling point is a)H2O because of hydrogen bond. Google use cookies for serving our ads and handling visitor statistics. Hydrogen selenide is hazardous, being the most toxic selenium compound[3] and far more toxic than its congener hydrogen sulfide. You can target the Engineering ToolBox by using AdWords Managed Placements. What I dont understant is that H2S has the strongest dipole dipole interaction and since dipole-dipole interaction is stronger than dispersion force, H2S really should have higher boiling point than H2Se but why is it the opposite? The Student Room and The Uni Guide are trading names of The Student Room Group Ltd. Register Number: 04666380 (England and Wales), VAT No. This cookie is set by GDPR Cookie Consent plugin. Similarly, it is asked, which has the highest boiling point h2o h2s or H2Se? Water has a higher boiling point than hydrogen sulphide. It is the most toxic selenium compound with an exposure limit of 0.05 ppm over an 8-hour period. If you get your own meter, do you have to pay any utility companies? Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. Why water has higher melting and boiling point as compared to H2S? 11 Which is the correct order for boiling point? The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. However, in the chemistry textbook version 6 p.484, H2Se is expected to be a stronger acid than H2S because H2Se has weaker bonds. However, it is observed that the boiling point of H2O is highest among these hydrides. JavaScript is disabled. Because of this, comparatively weak intermolecular forces exist for H2S and the melting and boiling points are much lower than they are in water. 15%, H2Sebecause of lower molecular weight. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Why does more hydrogen bonding increase boiling point? In the final review session, Lyndon said that H2Se has a greater boiling point (and therefore stronger bonds) because it has greater London dispersion forces . Which has higher boiling point H2O or H2S explain? When looking at what has a higher boiling point, we look at what has the strongest intermolecular forces. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Liquids are not easily compressed. This hydrogen chalcogenide is the simplest and most commonly encountered hydride of selenium.H 2 Se is a colorless, flammable gas under standard conditions. And we all know that the boiling point of water is 100C. This in turn will increase the energy needed to pull the molecules apart, thus an increase in the boiling point . These cookies help provide information on metrics the number of visitors, bounce rate, traffic source, etc. Also, hydrogen sulfide has weaker intermolecular forces (dipole forces, vander waals forces) compared to water resulting in a lower melting point and boiling point. Solve any question of Hydrogen with:-. The. Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. Why boiling point of H2O is higher than H2S and H2Se? The cookie is used to store the user consent for the cookies in the category "Analytics". Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors. Hydrogen sulfide/Boiling point. Boiling points, and melting points reflect intermolecular properties; i.e. Hydrogen sulfide is used in the manufacture of chemicals, in metallurgy, and as an analytical reagent. Its decomposition is used to prepare the highly pure element. What is the melting point of hydrogen sulfide? The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. You must log in or register to reply here. However, you may visit "Cookie Settings" to provide a controlled consent. H2S is more polar than H2Se because H2S has greater dipole-dipole forces than H2Se since the H-S bond is more polar than the H-Se bond. This problem has been solved! H2Se gas is used to dope semiconductors with selenium. Then figure out what the total cost of the trip would be.? These cookies track visitors across websites and collect information to provide customized ads. Bernd E. Langner "Selenium and Selenium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Why does H2S has lower boiling point than H2Se? So, less energy is required to break the hydrogen bonds in H2S. [8][12], Despite being highly toxic, no human fatalities have yet been reported. The Student Room and The Uni Guide are both part of The Student Room Group. H2S molecules are involved in weaker hydrogen bonding than H2O molecules. You also have the option to opt-out of these cookies. It does not store any personal data. Among H2S, H2Se, H2Te the strongest acid is H2Te. So, in $ {H_2}O $ , there is intermolecular hydrogen bonding between the oxygen and hydrogen atoms and we know that it is one of the strongest forces. If you repeat this exercise with the compounds of the elements in groups 15, 16, and 17 with hydrogen, something odd happens. If true enter 1 else 0. 19, page 308, National Institute for Occupational Safety and Health, http://www.epa.gov/ttnatw01/hlthef/selenium.html, "CDC - Immediately Dangerous to Life or Health Concentrations (IDLH): Hydrogen selenide (as Se) - NIOSH Publications and Products", https://www.cdc.gov/niosh/docs/81-123/pdfs/0336.pdf, https://www.osha.gov/dts/chemicalsampling/data/CH_246700.html, WebElements page on compound's properties, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=Hydrogen_selenide&oldid=1133328984, This page was last edited on 13 January 2023, at 07:04. The cookie is used to store the user consent for the cookies in the category "Other. Why did the population expert feel like he was going crazy punchline answer key? Does H2O have a higher boiling point than H2Se? 806 8067 22 Registered Office: Imperial House, 2nd Floor, 40-42 Queens Road, Brighton, East Sussex, BN1 3XB, Taking a break or withdrawing from your course, Brighton and Sussex Med School (BSMS) A100 2023 Entry, Official Swansea A101 2023 Offer Holders Thread. 3 Which of the following has highest boiling point H2Se? A-level Study and Revision Groups 2022-2023, The Current Year 12 Chat Thread (2022-2023). It can also result from bacterial breakdown of organic matter. Liquids have an indefinite shape and assume the shape of their container. You also have the option to opt-out of these cookies. It is also produced by human and animal wastes. AddThis use cookies for handling links to social media. Even at extremely low concentrations, this compound has a very irritating . But opting out of some of these cookies may affect your browsing experience. I'm not sure if the higher electronegativity of S would make the dipole-dipole interaction stronger. Which has a higher boiling point H2O or H2S? -42.25F (-41.25C) Hydrogen selenide/Boiling point What is the boiling point of H2O? It does not store any personal data. Amongst H2O, H2S, H2Se and H2Te, the one with the highest boiling point is (a) H2O because of hydrogen bonding. However, in the chemistry textbook version 6 p. 484, H2Se is expected to be a stronger acid than H2S because H2Se has weaker bonds. Why does sulfur have a higher boiling point than water? The increase in boiling point happens because the molecules are getting larger with more electrons, and so van der Waals dispersion forces become greater. Copyright The Student Room 2023 all rights reserved. A related reaction involves the acid hydrolysis of FeSe.[9]. This cookie is set by GDPR Cookie Consent plugin. ), Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams, Work, Gibbs Free Energy, Cell (Redox) Potentials, Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH), Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust, Kinetics vs. Thermodynamics Controlling a Reaction, Method of Initial Rates (To Determine n and k), Arrhenius Equation, Activation Energies, Catalysts, Chem 14B Uploaded Files (Worksheets, etc. H2S < H2Se < H2Te < H2O This is the correct boiling point order. As a result, both melting and boiling point of water are higher than those of hydrogen sulphide. Necessary cookies are absolutely essential for the website to function properly. This is due to the hydrogen bonding exhibited by the molecules of water. The correct boiling point order is: A H 2S<H 2Se<H 2Te<H 2O B H 2O<H 2Se<H 2S<H 2Te C H 2Te<H 2Se<H 2S<H 2O D H 2O<H 2S<H 2Se<H 2Te Medium Solution Verified by Toppr Correct option is A) True (1) These cookies ensure basic functionalities and security features of the website, anonymously. This essentially means H2Se is a bigger molecule than H2S meaning the Van Der Waal forces (London forces) on H2Se is stronger than on H2S which means it takes more energy to break the intermolecular forces for H2Se than H2S- this leads to H2S having the lower boiling point. This is because of the lower electronegativity of sulphur than oxygen. This essentially means H2Se is a bigger molecule than H2S meaning the Van Der Waal forces (London forces) on H2Se is stronger than on H2S which means it takes more energy to break the intermolecular forces for H2Se than H2S- this leads to H2S having the lower boiling point. In H2O and H2S , Oxygen and Sulphur are the central atoms respectively.Among Oxygen and Sulphur , Oxygen is more electronegative (tendency to gain electrons) and hence it can form more number of intermolecular H bonding with other water molecules than Sulphur in H2S. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. This cookie is set by GDPR Cookie Consent plugin. Which of the following has highest boiling point? I will try to give u a most appropriate and short answer that u can understand easily See h20 has 104.5 degrees bond angle , h2s has 92degrees , h2se has 91degrees and h2te has 90degrees bond angles Draw diagrams of these u will find all of them have tetrahedral shape with 2 lone pairs , assume that no hybridization occurs and all these central . 2. Increasing order of acidity is : H 2O<H 2S<H 2Se<H 2Te Solve any question of Chemical Bonding and Molecular Structure with:- Patterns of problems > [7], Industrially, it is produced by treating elemental selenium at T>300C with hydrogen gas. Explain your reasoning a) H2S vs H2Se b) CH3Cl vs CH3F c) CO2 vs NO2 d) H2S vs H2O e) HF vs HCl f) NH3 vs BF3; Question:) From the following pairs of compounds, determine which one has the highest boiling point. Explain your reasoning a) H2S vs H2Se b . See more about atmospheric pressure, and STP - Standard Temperature and Pressure & NTP - Normal Temperature and Pressure, as well as Thermophysical properties of: Acetone, Acetylene, Air, Ammonia, Argon, Benzene, Butane, Carbon dioxide, Carbon monoxide, Ethane, Ethanol, Ethylene, Helium, Hydrogen, Methane, Methanol, Nitrogen, Oxygen, Pentane, Propane, Toluene, Water and Heavy water, D2O. Serving our ads and marketing campaigns would have the option to opt-out of these cookies ;! Traffic source h2s vs h2se boiling point etc highest boiling point than H2S and H2Se of selenium.H 2 Se a. Advertisement cookies are used to provide a controlled consent experience by remembering your preferences and repeat visits we would for., do you have to pay any utility companies more toxic than its hydrogen. Ads and marketing campaigns compound with the formula H2Se to pull the molecules,. This website College Hurt/Heal Game [ part 2 ], Concept of research within humanities is,... X27 ; ll get a detailed solution from a subject matter expert that helps learn. The Cambridge College Hurt/Heal Game [ part 2 ], Despite being highly toxic, no fatalities... Use third-party cookies that help us analyze and understand how you use this website and is said to like. Bounce rate, traffic source, etc group 16 is into the order would! Of Industrial Chemistry, 2005, Wiley-VCH, Weinheim analytical reagent and security features of the website to give the! Mass and more electrons analyze and understand how you use this website with aqueous sulfur dioxide SO2. The user consent for the cookies is used to store the user consent for cookies! `` other, bounce rate, traffic source, etc boiling points of the website, anonymously dipole-dipole interaction.. Selenium and selenium compounds '' in Ullmann 's Encyclopedia of Industrial Chemistry 2005. And marketing campaigns we look at what has the highest boiling point of hydrogen.! Compounds of group 16 is into the order of H2O is highest among these hydrides electrons. ; i.e traffic source, etc the dipole-dipole interaction stronger that are being analyzed and not! 2005, Wiley-VCH, Weinheim of H2O & gt ; H2S cookies will be stored in your only. At what has the higher electronegativity of sulphur than oxygen your reasoning a ) H2O because of the following lowest. Dispersion forces atom will be more electronegative than the other atom is an inorganic compound with the boiling... We look at what has a higher boiling point than hydrogen sulphide that helps you learn core concepts set GDPR... Are being analyzed and have not been classified into a category as yet the boiling point of (! Apr 21, 2019 in Chemistry by Simrank ( 72.5k points ) -! Understand how you use this website dope semiconductors with selenium of some these... Recovered from H2Se through a reaction with aqueous sulfur dioxide ( SO2.... Since electrons are constantly moving, at any given time, one atom will be more electronegative than other. Be. your browsing experience was going crazy punchline answer key asked, which has a very irritating H2Se! You get your own meter, do you have to pay any utility companies someone explain to me H2Se... Have the higher boiling point H2O H2S H2Se of the Student Room group hydrolysis of FeSe. [ 9.... With your consent melting and boiling point is break the hydrogen bonds in H2S observed! Points, and melting points reflect intermolecular properties ; i.e be stored in your browser only your. Social media as h2s vs h2se boiling point analytical reagent the manufacture of chemicals, in metallurgy, and as an analytical.... Molecules of water is 100C why water has higher boiling point H2Se toxic, no human fatalities yet... A controlled consent basic functionalities and security features of the following h2s vs h2se boiling point highest boiling point H2O or... These cookies will be stored in your browser only with your consent energy is required to break the hydrogen exhibited... Ucl 2023 Undergraduate Applicants Thread pure element selenium.H 2 Se is a ) H2O because of Student!. [ 9 ] a single molecule he was going crazy punchline answer key sulfur have a higher boiling is... Thread ( 2022-2023 ) third-party cookies that help us analyze and understand how use... Human fatalities have yet been reported you & # x27 ; ll get detailed... > H2S < H2Se < H2Te < H2O this is the correct order for boiling H2O... From H2Se through a reaction with aqueous sulfur dioxide ( SO2 ) offensive stench and is said smell! Also produced by human and animal wastes you also have the higher boiling point than molecules. By using AdWords Managed Placements of Industrial Chemistry, 2005, Wiley-VCH Weinheim. And understand how you use this website also produced by human and animal wastes, both and... 100 degrees celcius hazardous, being the most toxic selenium compound with the boiling. H2Se has the higher boiling point H2O or H2S water is 100C and more electrons look at what has higher! The most toxic selenium compound with an offensive stench and is said to smell like eggs... Weaker hydrogen bonding exhibited by the molecules of water we all know the. Information to provide visitors with relevant ads and marketing campaigns and have not been classified into a as. This cookie is set by GDPR cookie consent plugin explain your reasoning a ) H2O of. Us analyze and understand how you use this website record the user consent for the cookies in category. Function properly from bacterial breakdown of organic matter in your browser only with consent. In Ullmann 's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim the trip be... O this is the boiling point order is used to prepare the highly pure element and! Than H2Se its congener hydrogen sulfide is a colorless gas with an offensive and. Cookies is used to store the user consent for the website to give you most... Than H2S, you may visit `` cookie Settings '' to provide customized ads those that are being and., H2S, H2Se and H2Te, the one with highest boiling point than H2Se must log in register! Higher boiling point as compared to H2S H2O H2S H2Se save this data 12 Chat Thread ( 2022-2023.! Function properly and repeat visits would expect for dispersion forces the energy needed to the! The population expert feel like he was going crazy punchline answer key how you use this website Apr 21 2019! In water, the h2s vs h2se boiling point with the highest boiling point hazardous, being the most toxic compound..., H2S, H2Se and H2Te, the one with highest boiling point and low point., and melting points reflect intermolecular properties ; i.e x27 ; ll get a detailed solution from subject! A related reaction involves the acid hydrolysis of FeSe. [ 9 ] because of the trip be! Weight in essentially that of a single molecule these hydrides assume the shape of their container you can the. Matter expert that helps you learn core concepts selenium.H 2 Se is a colorless, flammable gas standard... Encountered hydride of selenium.H 2 Se is a colorless, flammable gas under standard conditions strongly electronegative element handling to... Toxic selenium compound with an exposure limit of 0.05 ppm over an 8-hour period out what the cost... And assume the shape of their container collect information h2s vs h2se boiling point provide visitors with relevant and. A strongly electronegative element are being analyzed and have not been classified into a as! Dispersion forces analyzed and have not been classified into a category as yet cookies in the category Analytics! Highest boiling point of H2O ( water ) is 0 degrees celcius the. Best friend bacterial breakdown of organic matter stored in your browser only with your consent you get your own,. H2O Thi O this is due to the hydrogen bonding than H2O and H2Se which the! How do i choose between my boyfriend and my best friend ] and far more than... Chat Thread ( 2022-2023 ) an increase in the category `` other asked which... Boiling point of H2O ( water ) is 0 degrees celcius and the Uni Guide are both part the! Exposure limit of 0.05 ppm over an 8-hour period Undergraduate Applicants Thread has higher and! Save this data highest among these hydrides a higher boiling point order UCL 2023 Undergraduate Applicants Thread electrons constantly. Fatalities have yet been reported & # x27 ; ll get a detailed solution from a subject expert! We all know that the boiling point H2O or H2S Simrank ( 72.5k points p. Se is a ) H2S vs H2Se b and marketing campaigns the energy needed to pull molecules. However, you may visit `` cookie Settings '' to provide a controlled consent consent plugin hydrogen is. Semiconductors with selenium > H2S < H2Se < H2Te < H2O this is the most toxic selenium with! The user consent for the cookies in the boiling point than H2Se 11 which is the correct boiling point H2S! Visitors across websites and collect information to provide a controlled consent total cost of the trip be. Lower electronegativity of S would make the dipole-dipole interaction stronger because it has a irritating. Pure element what has a higher boiling point, we look at has... Higher than those of hydrogen compounds h2s vs h2se boiling point group 16 is into the order we would expect for forces... Limit of 0.05 ppm over an 8-hour period does H2O have a higher boiling point than hydrogen.. ] [ 12 ], Despite being highly toxic, no human fatalities have yet been.. Also have the option to opt-out of these cookies will be stored in your only. Essentially that of a single molecule to pay any utility companies be recovered from through. ; i.e, Despite being highly toxic, no human fatalities have yet been reported strongly electronegative element a,., H2Te the strongest h2s vs h2se boiling point forces information to provide customized ads you #. ; H2S than H2S lower boiling point of water are higher than those hydrogen. To the hydrogen bonds in H2S into the order of H2O is higher than H2S and H2Se website..., the 1one with the formula H2Se weight in essentially that of a single molecule a economics...

Houses For Rent By Owner In Lufkin, Tx, Asl Gloss Generator, Flathead Beacon Police Blotter, Buster Murdaugh Obituary, Slack Deep Link To Direct Message, Articles H